• 文献标题:   Synthesis of hydrogenated TiO2-reduced-graphene oxide nanocomposites and their application in high rate lithium ion batteries
  • 文献类型:   Article
  • 作  者:   WANG J, SHEN LF, NIE P, XU GY, DING B, FANG S, DOU H, ZHANG XG
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Nanjing Univ Aeronaut Astronaut
  • 被引频次:   29
  • DOI:   10.1039/c4ta00657g
  • 出版年:   2014

▎ 摘  要

A hydrogenated TiO2-reduced-graphene oxide (H-TiO2-RGO) nanocomposite is synthesised via a facile one-pot hydrogenation treatment process. The morphologies and structures are characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). The nitrogen adsorption-desorption isotherms revealed that the H-TiO2-RGO exhibited large specific surface area of 114.4 m(2) g(-1). Compared with the TiO2-RGO nanocomposite, the H-TiO2-RGO nanocomposite exhibits a much higher rate capability and better capacity retention. At a current rate of 5 C, the reversible capacity of the H-TiO2-RGO electrode is up to 166.3 mA h g(-1) and with only 2.4% capacity loss after 100 cycles. The excellent electrochemical performance is strongly related to the high electronic conductivity derived from hydrogenated TiO2 frameworks and the good contact between the zero-dimensional (0D) H-TiO2 nanoparticles with two-dimensional (2D) reduced-graphene oxide nanosheets, which efficiently shortened the Li+ diffusion path lengths, enhanced the electrolyte-active material contact area and facilitated rapid e(-) transfer.