• 文献标题:   Enhanced high-rate discharge properties of La11.3Mg6.0Sm7.4Ni61.0Co7.2Al7.1 with added graphene synthesized by plasma milling
  • 文献类型:   Article
  • 作  者:   OUYANG LZ, CAO ZJ, LI LL, WANG H, LIU JW, MIN D, CHEN YW, XIAO FM, TANG RH, ZHU M
  • 作者关键词:   hydrogenstorage alloy, highrate discharge propertie, kinetic, ni/mh batterie
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   S China Univ Technol
  • 被引频次:   126
  • DOI:   10.1016/j.ijhydene.2014.06.111
  • 出版年:   2014

▎ 摘  要

In order to improve the high-rate discharge properties of La11.3Mg6.0Sm7.4Ni61.0Co7 Al-2(7.1) (AB(3.0)) alloy electrodes, the effects of plasma milling (PM) and graphene addition on their electrochemical properties and kinetics have been investigated. It was found that the discharge capacity of AB(3.0) at a high discharge current density was significantly improved after the addition of graphene followed by PM for only 10 min. Moreover, the high-rate dischargeability (HRD) and the exchange current density I-o of the alloy electrodes were also increased. The PM technique exhibits obvious advantages for improving the high-rate discharge properties of hydrogen-storage alloys. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.