• 文献标题:   Synthesis and characterization of graphene-mesoporous silica nanoparticle hybrids
  • 文献类型:   Article
  • 作  者:   GUARDIA L, SUAREZGARCIA F, PAREDES JI, SOLISFERNANDEZ P, ROZADA R, FERNANDEZMERINO MJ, MARTINEZALONSO A, TASCON JMD
  • 作者关键词:   graphene, mesoporous silica nanoparticle, soft templating
  • 出版物名称:   MICROPOROUS MESOPOROUS MATERIALS
  • ISSN:   1387-1811 EI 1873-3093
  • 通讯作者地址:   INCAR CSIC
  • 被引频次:   22
  • DOI:   10.1016/j.micromeso.2012.04.038
  • 出版年:   2012

▎ 摘  要

We report the synthesis of graphene-mesoporous silica nanoparticle (MSN) hybrids by selective growth of the latter on graphene oxide sheets using a cationic surfactant-templated method. The MSNs were just a few tens of nanometers in size, exhibited internal mesopores similar to 3.7-4 nm wide and appeared to be firmly attached to the graphene sheets. The nanoparticles could also be produced with varying densities on the graphene support, from isolated entities up to close-packed monolayers uniformly coating both sides of the sheets, which allowed fine-tuning the porous texture of the materials on the basis of their interparticle porosity. The experimental conditions that afford the generation of these graphene-MSN hybrids are also discussed. (C) 2012 Elsevier Inc. All rights reserved.