• 文献标题:   Graphene quantum dots: Highly active bifunctional nanoprobes for nonenzymatic photoluminescence detection of hydroquinone
  • 文献类型:   Article
  • 作  者:   HE YZ, SUN J, FENG DX, CHEN HQ, GAO F, WANG L
  • 作者关键词:   graphene quantum dot, peroxidasemimicking catalytic activity, photoluminescence, hydroquinone
  • 出版物名称:   BIOSENSORS BIOELECTRONICS
  • ISSN:   0956-5663 EI 1873-4235
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   28
  • DOI:   10.1016/j.bios.2015.07.006
  • 出版年:   2015

▎ 摘  要

In this paper, a simple and sensitive photoluminescence method is developed for the hydroquinone quantitation by using graphene quantum dots which simultaneously serve as a peroxidase-mimicking catalyst and a photoluminescence indicator. In the presence of dissolved oxygen, graphene quantum dots with intrinsic peroxidase-mimicking catalytic activity can catalyze the oxidation of hydroquinone to produce p-benzoquinone, an intermediate, which can efficiently quench graphene quantum dots' photoluminescence. Based on this effect, a novel fluorescent platform is proposed for the sensing of hydroquinone, and the detection limit of 5 nM is found. (C) 2015 Elsevier B.V. All rights reserved.