• 文献标题:   Prussian Blue Nanoparticles Self Assembling on Electrochemically Reduced Graphene Oxide Modified GC Electrode for Sensitive Hydrogen Peroxide Detection
  • 文献类型:   Article
  • 作  者:   RAZMI H, JABBARI M, MOHAMMADREZAEI R
  • 作者关键词:   prussian blue, reduced graphene oxide, hydrogen peroxide, modified electrode
  • 出版物名称:   JOURNAL OF THE CHINESE CHEMICAL SOCIETY
  • ISSN:   0009-4536 EI 2192-6549
  • 通讯作者地址:   Azarbaijan Shahid Madani Univ
  • 被引频次:   4
  • DOI:   10.1002/jccs.201200621
  • 出版年:   2013

▎ 摘  要

A facile, fast, and convenient route was suggested for the fabrication of Prussian blue nano particles (PBNPs) assembled on reduced graphene oxide (RGO) modified glassy carbon electrode (PBNPs|RGO|GCE). RGO was electrodeposited on the surface of GCE and the prepared RGO|GCE was immersed into a ferric-hexacyanoferrate(III) solution and PBNPs were assembled on the RGO|GCE for a certain period of time. The PBNPs film thickness can be easily controlled by adjusting the assembling duration. The developed PBNPs|RGO|GCE was successfully used for determining hydrogen peroxide, with a linear response over the concentration range 0.5-400 M, a good accuracy and precision, detection limit 0.44 M, and sensitivity 1168 mA M-1 cm(-2).