• 文献标题:   Vanadium salt assisted solvothermal reduction of graphene oxide and the thermoelectric characterisation of the reduced graphene oxide in bulk and as composite
  • 文献类型:   Article
  • 作  者:   GNANASEELAN M, SAMANTA S, PIONTECK J, JEHNICHEN D, SIMON F, POTSCHKE P, VOIT B
  • 作者关键词:   polymer, composite, nanomaterial, functional material, energy material
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584 EI 1879-3312
  • 通讯作者地址:   Leibnix Inst Polymerforsch Dresden eV IPF
  • 被引频次:   3
  • DOI:   10.1016/j.matchemphys.2019.03.002
  • 出版年:   2019

▎ 摘  要

The solvothermal reduction of graphene oxide (GO), modified by the addition of vanadium chloride, resulted in an increased reduction degree of the reduced graphene oxide (rGO), which is reflected by a remarkably increased electrically conductivity of up to 8.5 S/cm, a value 30 times higher than that of rGO prepared without vanadium salt addition. Parallel with this increase, the thermoelectrical properties of rGO are improved, with a reached maximum Seebeck coefficient of 13.7 mu V/K. The rGOs were used as fillers in flexible styrene-butadiene-styrene triblock copolymer composites prepared by solution mixing. Compared to the traditionally prepared reduced graphene oxide, the new product provides up to 60 times higher conductivity to the composite, while the Seebeck coefficient is nearly the same. The highest power factor of 4.6 x 10(-4) mu W/(m.K-2) was achieved at 100 degrees C with 30 wt% loading, which is 30 times higher than that of the traditional reduced graphene oxide containing composite.