• 文献标题:   Picomolar detection of mercury (II) using a three-dimensional porous graphene/polypyrrole composite electrode
  • 文献类型:   Article
  • 作  者:   WANG M, YUAN WJ, YU XW, SHI GQ
  • 作者关键词:   polypyrrole, reduced graphene oxide, hg2+ ion, porous electrode
  • 出版物名称:   ANALYTICAL BIOANALYTICAL CHEMISTRY
  • ISSN:   1618-2642 EI 1618-2650
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   14
  • DOI:   10.1007/s00216-014-7871-z
  • 出版年:   2014

▎ 摘  要

A polypyrrole (PPy)-functionalized three-dimensional (3D) porous electrode of electrochemically reduced graphene oxide (ErGO) has been prepared by electrochemical deposition. This PPy-modified 3D-ErGO electrode was used for the electrochemical detection of Hg2+ ions, and it exhibited high sensitivity and selectivity. Furthermore, the limit of detection (LOD) was measured to be as low as 0.03 nM (30 ppt), and this value is much lower than the guideline value of 2 ppb for drinking water given by the World Health Organization.