• 文献标题:   Controllable preparation of graphene/MnO2/Co3O4 for supercapacitors
  • 文献类型:   Article
  • 作  者:   HAN LX, XU ZF, WU J, GUO XQ, ZHU HL, CUI HZ
  • 作者关键词:   graphene, mno2/co3o4, nanocomposite, supercapacitor, specific capacitance
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Shandong Univ Sci Technol
  • 被引频次:   20
  • DOI:   10.1016/j.jallcom.2017.09.251
  • 出版年:   2017

▎ 摘  要

Graphene was successfully prepared using LLDPE (Linear Low-Density Polyethylene) plastic particles as carbon source via a CVD process, and then combined with MnO2/Co3O4 composite prefabricated in our experiment to test the electrochemical performance for supercapacitors. MnO2/Co3O4 has the largest CV area and suggests a larger capacitance potential. The discharge curve of MnO2/Co3O4 is close to that of MnO2, indicating that the capacitance of MnO2/Co3O4 is dominated by MnO2, and the discharge of Graphene/MnO2/Co3O4 is slow at high voltage. The addition of graphene improves specific capacitance of MnO2/Co3O4 electrode materials, reaching 502.3 F/g at current density of 1 A/g. After 1000 charge/discharge cycles, the capacitance of all the materials synthesized in this study remains over 94.7% at the current density of 10 A/g, suggesting great potential for supercapacitors and one can choose the proper material according to various applications. (C) 2017 Published by Elsevier B.V.