• 文献标题:   A novel 'bottom-up' synthesis of few- and multi-layer graphene platelets with partial oxidation via cavitation
  • 文献类型:   Article
  • 作  者:   PRICE RJ, LADISLAUS PI, SMITH GC, DAVIES TJ
  • 作者关键词:   cavitation, graphene, hydrodynamic, functionalisation, synthesi, ultrasound
  • 出版物名称:   ULTRASONICS SONOCHEMISTRY
  • ISSN:   1350-4177 EI 1873-2828
  • 通讯作者地址:   Univ Chester
  • 被引频次:   1
  • DOI:   10.1016/j.ultsonch.2019.03.020
  • 出版年:   2019

▎ 摘  要

The transient cavitation of diaromatic components such as 1-methylnaphthalene has been used to produce graphene platelets in a 'bottom-up' synthesis via the high temperature (> 5000 K) conditions that are generated inside collapsing bubbles. Acoustic cavitation produced yields of 5.7 x 10(-11) kgJ(-1) at a production rate of 2.2 x 10(-9) kgs(-1). This can be improved by generating cavitation hydrodynamically, thus making commercial scale production viable. Hydrodynamic cavitation produced platelets with larger lateral dimensions (>= 2 mu m) than those formed by acoustic cavitation (10-200 nm). The partially oxidised nature of the platelets enables their covalent chemical functionalisation, which was achieved by combining suitable molecules in the reaction medium to affect a one-pot formation and functionalisation of graphene.