• 文献标题:   Mechanical properties of epoxy composites reinforced with ammonia-treated graphene oxides
  • 文献类型:   Article
  • 作  者:   PARK MS, LEE S, LEE YS
  • 作者关键词:   graphene oxide, nitrogen, surface treatment, epoxy composite, mechanical propertie
  • 出版物名称:   CARBON LETTERS
  • ISSN:   1976-4251 EI 2233-4998
  • 通讯作者地址:   Chungnam Natl Univ
  • 被引频次:   18
  • DOI:   10.5714/CL.2017.21.001
  • 出版年:   2017

▎ 摘  要

The effects of ammonia-treated graphene oxide (GO) on composites based on epoxy resin were investigated. Ammonia solutions of different concentrations (14-28%) were used to modify GO. Nitrogen functional groups were introduced on the GO surfaces without significant structural changes. The ammonia-treated GO-based epoxy composites exhibited interesting changes in their mechanical properties related to the presence of nitrogen functional groups, particularly amine (C-NH2) groups on the GO surfaces. The highest tensile and impact strength values were 42.1 MPa and 12.3 J/m, respectively, which were observed in an epoxy composite prepared with GO treated with a 28% ammonia solution. This improved tensile strength was 2.2 and 1.3 times higher than those of the neat epoxy and the non-treated GO-based epoxy composite, respectively. The amine groups on the GO ensure its participation in the cross-linking reaction of the epoxy resin under amine curing agent condition and enhance its interfacial bonding with the epoxy resin.