• 文献标题:   A hybrid sorbent of alpha-iron oxide/reduced graphene oxide: Studies for adsorptive removal of tetracycline antibiotics
  • 文献类型:   Article
  • 作  者:   ZOU SJ, CHEN YF, ZHANG Y, WANG XF, YOU N, FAN HT
  • 作者关键词:   tetracycline antibiotic, nanocomposite, graphene, iron oxide
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   28
  • DOI:   10.1016/j.jallcom.2020.158475 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Tetracyclines antibiotics (TAs), a veterinary drug used widely, has greatly attracted the attention due to its potential threats. We report the nanocomposites of the alpha-Fe2O3 nanoparticles growth on reduced graphene oxide (RGO) by a one-pot method. The adsorptive amounts (216.2 mg g(-1) for chlortetracycline, 180.8 mg g(-1) for tetracycline and 98.4 mg g(-1) for oxytetracycline) of the alpha-Fe2O3 @RGO nanocomposites was mainly correlated with the increasement of the uniform and well-dispersed alpha-Fe2O3 nanoparticles on RGO. The relatively low adsorptive amount of oxytetracycline is due to the synergetic effect of its relatively weak interactions with RGO and relatively slack complexation with alpha-Fe2O3, which also provides an experimental proof for the theoretical prediction previously reported. The TAs adsorption by the alpha-Fe2O3 @RGO nanocomposites is achieved for 20 min and strongly pH-dependent due to the enhanced repulsive interaction at low or high pH. The TAs adsorptions fitted well the Langmuir and the pseudo-second-order equations. (C) 2020 Elsevier B.V. All rights reserved.