• 文献标题:   The Optical and Electrical Properties of Graphene Oxide with Water-Soluble Conjugated Polymer Composites by Radiation
  • 文献类型:   Article
  • 作  者:   JUNG ST, OH SH, BIN KIM H, JEUN JP, LEE BJ, KANG PH
  • 作者关键词:   graphene oxide, radiation, optical, electrical property
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Korea Atom Energy Res Inst
  • 被引频次:   8
  • DOI:   10.1166/jnn.2013.7854
  • 出版年:   2013

▎ 摘  要

In order to overcome the difficulty of dispersion and low conductivity in composite containing graphene, graphene oxide (GO) has been used instead of neat graphene. And the GO treated by radiation, could give improved conductivity of the GO-containing polymer composite. In this study, fluorene based water-soluble conjugated polymer (WPF-6-oxy-F) was introduced in GO solution to investigate the change of optical and electrical properties through radiation process. UV-Vis absorption of irradiated WPF-6-oxy-F-GO composite was red shifted and I(D)/I(G)ratio of Raman spectra decreased. XPS analysis showed that C-N bonds was formed after the irradiation and confirmed the increased bonds between the GO and the water-soluble conjugated polymer matrix. From the AFM and XPS analysis, it was found that the water-soluble conjugated polymer matrix was stacked between the modified GO in the morphology of irradiated WPF-6-oxy-F-GO composite was increased after gamma ray irradiation up to 10(-2) S/cm.