• 文献标题:   Reassessing Graphene Absorption and Emission Spectroscopy
  • 文献类型:   Article
  • 作  者:   YANG Y, KOLESOV G, KOCIA L, HELLER EJ
  • 作者关键词:   graphene, condensed matter spectroscopy, uvvis spectroscopy, optical absorption, optical emission
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Harvard Univ
  • 被引频次:   4
  • DOI:   10.1021/acs.nanolett.7b02500
  • 出版年:   2017

▎ 摘  要

We present a new paradigm for understanding optical absorption and hot electron dynamics experiments in graphene. Our analysis pivots on assigning proper importance to phonon-assisted indirect processes and bleaching of direct processes. We show indirect processes figure in the excess absorption in the UV region. Experiments which were thought to indicate ultrafast relaxation of electrons and holes, reaching a thermal distribution from an extremely nonthermal one in under 5-10 fs, instead are explained by the nascent electron and hole distributions produced by indirect transitions. These need no relaxation or ad-hoc energy removal to agree with the observed emission spectra and fast pulsed absorption spectra. The fast emission following pulsed absorption is dominated by phonon-assisted processes, which vastly outnumber direct ones and are always available, connecting any electron with any hole any time. Calculations are given, including explicitly calculating the magnitude of indirect processes, supporting these views.