▎ 摘　　要

Heterointegration of graphene with silicon has attracted growing interest, because the resulting unique heterojunction allows for efficient collection of light generated electron-hole pairs. This study aims to understand the role of device fabrication conditions and electronic properties of chemically doped graphene on the efficiency variations and stability of graphene/silicon solar cells. We observed significant variations in the efficiency between the devices doped with metal chloride and organic molecules. A strong degradation in the hole carrier mobility by the formation of metal particles/clusters, which could act like charge puddles, accounts for the limited efficiency in the former. Molecular doping, on the other hand, offered good doping homogeneity and no mobility degradation, leading to solar cells with efficiency as high as 9.2%. Our results demonstrate that the droop in efficiency over time observed in the chemically doped devices is due to oxidation limited charge carrier separation rather than doping reversal. The prospects of molybdenum oxide (MoOx) as a multifunctional layer in improving the device stability and efficiency are also discussed based on preliminary experimental findings.