• 文献标题:   Tetranitro-substituted cobalt phthalocyanine immobilized on reduced graphene oxide as supercapacitor electrode material with enhanced capacitance
  • 文献类型:   Article
  • 作  者:   QI F, WANG Y, XU JY, WANG X, WANG JJ, SHAN HQ, LI MZ, XU JJ
  • 作者关键词:   cobalt phthalocyanine, reduced graphene oxide, nanocomposite, specific capacitance
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.synthmet.2023.117284 EA JAN 2023
  • 出版年:   2023

▎ 摘  要

Recent progress in the construction of metal phthalocyanines (MPcs) has opened up new strategies for energy storage applications. Since MPcs possess excellent redox activities, we have developed a simple ultrasound process to fabricate nanocomposites based on different ratios of tetranitro-substituted cobalt phthalocyanine (Co (NO2)4Pc) and reduced graphene oxide (rGO) and evaluated their energy storage performance for super -capacitor. A maximum specific capacitance of 150.22 F g-1 was achieved for the Co(NO2)4Pc-rGO 1/6 electrode at high current density (4 A g-1), which is 1.6 and 1.8 times higher than the individual materials, respectively. This great electrochemical activity is attributed to the synergistic effect between two components. Moreover, this electrode manifested outstanding cycling stability (retained 111.6 % of its initial capacitance after 5000 cycles). The experimental findings ensure the potential application of Co(NO2)4Pc-rGO composite as an electrode ma-terial for the next-generation supercapacitor applications.