• 文献标题:   Influence of Concentration and Electrodeposition Time on the Electrochemical Supercapacitor Performance of Poly(3,4-Ethylenedioxythiophene)/Graphene Oxide Hybrid Material
  • 文献类型:   Article
  • 作  者:   AZMAN NHN, LIM HN, SULAIMAN Y
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF NANOMATERIALS
  • ISSN:   1687-4110 EI 1687-4129
  • 通讯作者地址:   Univ Putra Malaysia
  • 被引频次:   1
  • DOI:   10.1155/2016/5935402
  • 出版年:   2016

▎ 摘  要

Poly(3,4-ethylenedioxythiophene)/graphene oxide (PEDOT/GO) composites with wrinkled paper-like sheets morphology were electropolymerized potentiostatically at 1.2V with different electrodeposition times (1-30 min) and various concentrations of GO (0.5, 1.0, 1.5, and 2.0 mg/mL). The electrochemical properties of PEDOT/GO composites as an electrode material for supercapacitor were investigated using cyclic voltammetry, electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge (GCD). The CV results revealed that PEDOT/GO containing 1.0 mg/mL GO and electropolymerized for 10 minutes exhibited the highest specific capacitance (157.17 F/g). This optimum PEDOT/GO was found to have energy and power density of 18.24 W/kg and 496.64 Wh/kg, respectively, at 1.0 A/g current density. The resistance of charge transfer obtained for PEDOT/GO is very low (13.10 Omega) compared to PEDOT (638.98 Omega), proving that PEDOT/GO has a good supercapacitive performance due to the synergistic effect of the high conductivity of PEDOT and large surface area of GO.