• 文献标题:   Noncovalent Functionalization of Graphene and Graphene Oxide for Energy Materials, Biosensing, Catalytic, and Biomedical Applications
  • 文献类型:   Review
  • 作  者:   GEORGAKILAS V, TIWARI JN, KEMP KC, PERMAN JA, BOURLINOS AB, KIM KS, ZBORIL R
  • 作者关键词:  
  • 出版物名称:   CHEMICAL REVIEWS
  • ISSN:   0009-2665 EI 1520-6890
  • 通讯作者地址:   Ulsan Natl Inst Sci Technol
  • 被引频次:   721
  • DOI:   10.1021/acs.chemrev.5b00620
  • 出版年:   2016

▎ 摘  要

This Review focuses on noncovalent functionalization of graphene and graphene oxide with various species involving biomolecules, polymers, drugs, metals and metal oxide-based nanoparticles, quantum dots, magnetic nanostructures, other carbon allotropes (fullerenes, nanodiamonds, and carbon nanotubes), and graphene analogues (MoS2, WS2). A brief description of pi-pi interactions, van der Waals forces, ionic interactions, and hydrogen bonding allowing noncovalent modification of graphene and graphene oxide is first given. The main part of this Review is devoted, to tailored functionalization for applications in drug delivery, energy materials, solar cells, water splitting, biosensing, bioimaging, environmental, catalytic, photocatalytic, and biomedical technologies. A significant part of this Review explores the possibilities of graphene/graphene oxide-based 3D superstructures and their use in lithium-ion batteries. This Review ends with a look at challenges and future prospects of noncovalently modified graphene and graphene oxide.