▎ 摘　　要

In this study, a novel scalable method based on hydrothermal-assisted ball milling was used to simultaneously synthesize and amino-functionalize molybdenum disulfide nanosheets with diaminodiphenyl sulfone (DDS-MoS2). This process resulted in the production of the functionalized nanosheets with a lateral dimension of similar to 600-900 nm and thickness of similar to 2-6 nm without requiring a lithium intercalation step. The inverse gas chromatography results revealed that total surface energies of the nanosheets significantly increased after DDS functionalization, making them highly compatible with epoxy resin. Epoxy nanocomposites containing 0.5 wt% of DDS-MoS2 nanosheets showed similar to 30% and similar to 28% increases in tensile and flexural strengths, respectively. Additionally, similar to 16% and similar to 12% enhancements in tensile and flexural modulus, respectively, were observed in these nanocomposites. The inclusion of DDS-MoS2/epoxy resin in carbon fibre composites led to the fabrication of multiscale nanocomposites with improved mechanical properties. In these multiscale nanocomposites, flexural modulus and strength were considerably improved by similar to 33.7% and similar to 29.5%, respectively. Compared to other two-dimensional nanomaterials, such as nanoclay and graphene derivatives, DDS-MoS2 nanosheets showed promising behaviour for both epoxy nanocomposites and multiscale carbon fibre nanocomposites. These achievements could be associated with the synergistic effect of DDS-MoS2 in both promoting the interfacial stress transfer and the energy dissipation through different crack retardation mechanisms.