• 文献标题:   Sol-Gel Autocombustion Synthesis of Graphene/Cobalt Magnetic Nanocomposites
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   ZHANG L, HUANG Y, ZHANG Y, MA YF, CHEN YS
  • 作者关键词:   graphene, cobalt, sol gel method, citric acid, in situ synthesi
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Nankai Univ
  • 被引频次:   5
  • DOI:   10.1166/jnn.2013.6000
  • 出版年:   2013

▎ 摘  要

Here we describe a versatile new strategy for producing graphene/cobalt magnetic nanocomposites by combining the sol-gel method and autocombustion. We used graphene oxide (GO), cobalt nitrate and citric acid as starting materials and prepared a dry gel of them through a routine sol-gel approach. After the autocombustion was activated at 300 degrees C in a tube furnace under an argon atmosphere, reducing agents such as H-2 and CH4 were produced and then in situ reduced GO and cobalt nitrate to get graphene/cobalt magnetic nanocomposites. X-ray photoelectron spectroscopic and X-ray powder diffraction analysis showed that the nanoparticles loaded on graphene are cobalt but not cobalt oxide. Transmission electron microscopy and scanning electron microscopy revealed that cobalt nanoparticles, with an average diameter of similar to 10 nm, were homogeniously deposited on the surface of graphene. Further more, other metal nanoparticles such as Ni, Cu, Ag and Bi can also be loaded on graphene using the same method.