• 文献标题:   Cleverly embedded CoS2/NiS2 on two-dimensional graphene nanosheets as high-performance anode material for improved sodium ion batteries and sodium ion capacitors
  • 文献类型:   Article
  • 作  者:   LIU J, XU YG, KONG LB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Lanzhou Univ Technol
  • 被引频次:   1
  • DOI:   10.1007/s10854-020-03541-1 EA MAY 2020
  • 出版年:   2020

▎ 摘  要

The CoS2/NiS2-RGO composite with excellent electrochemical performance is first used as an anode material for sodium-ion capacitors (SICs) and sodium-ion batteries (SIBs). CoS2/NiS2-RGO is prepared by one-step hydrothermal process. In half-cell tests, CoS2/NiS2-RGO exhibits a remarkably high reversible capacity of 473.7 mA h g(-1) after 50 cycles at the specific current of 100 mA g(-1). SICs show an impressive energy density of 139.1 W h kg(-1) at the power density of 14,000 W kg(-1), which has great advantages compare to the commercial lithium ion batteries. SIBs also show a good capacity of 50 mA h g(-1) at a rate of 5 degrees C. The excellent electrochemical performance of CoS2/NiS2-RGO is mainly attributed to the heterostructure formed by CoS2 and NiS2, which effectively improves the electrical conductivity. On the other hand, there is a good synergistic effect between RGO and CoS2/NiS2. The large specific surface area of RGO makes CoS2/NiS2 disperse uniformly on the surface of RGO, preventing agglomeration and reducing particle size of CoS2/NiS2. In turn, CoS2/NiS2 acting on the surface layer of RGO hinders the secondary overlap and increases the electrical conductivity of RGO. The mixed bimetallic sulfide/RGO system is expected to promote the rapid development of sodium storage devices.