• 文献标题:   Brominated Graphene as Mimetic Peroxidase for Sulfide Ion Recognition
  • 文献类型:   Article
  • 作  者:   SINGH S, MITRA K, SHUKLA A, SINGH R, GUNDAMPATI RK, MISRA N, MAITI P, RAY B
  • 作者关键词:  
  • 出版物名称:   ANALYTICAL CHEMISTRY
  • ISSN:   0003-2700 EI 1520-6882
  • 通讯作者地址:   Banaras Hindu Univ
  • 被引频次:   24
  • DOI:   10.1021/acs.analchem.6b03535
  • 出版年:   2017

▎ 摘  要

Brominated graphene (GBR) with-,3% bromine content has shown novel peroxidase mimetic activity toward.3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2. Optimum activity has been observed at pH 4.48 and after a minimum similar to 30 min of equilibration time. Among the different analVtes studied using the sensor combining TMB,. H2O2, and GBR in phosphate buffer of pH 4.48, the S2- ion has effectively shown a short duration of sensing (similar to 2 min) within the detection range of 0.04-1 m.M. A calibration curve for S2- ion estimation has been constructed with the experimental linearity in 0.04-0.4 mM range and having the limit of detection (LOD) value of 25.3 mu M. A standard addition experiment has validated the method. A paper strip sensor has been fabricated for successful detection of S2- ion.