• 文献标题:   Supported molybdenum on graphene oxide/Fe3O4: An efficient, magnetically separable catalyst for one-pot construction of spiro-oxindole dihydropyridines in deep eutectic solvent under microwave irradiation
  • 文献类型:   Article
  • 作  者:   ZHANG M, LIU YH, SHANG ZR, HU HC, ZHANG ZH
  • 作者关键词:   graphene oxide, magnetic nanoparticle, deep eutectic solvent, multicomponent reaction, spirooxindole dihydropyridine, microwave irradiation
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Hebei Normal Univ
  • 被引频次:   76
  • DOI:   10.1016/j.catcom.2016.09.028
  • 出版年:   2017

▎ 摘  要

Magnetically separable graphene oxide supported molybdenum (Fe3O4/GO-Mo) nanoparticles were prepared and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometry (VSM) techniques. The synthesized heterogeneous material was found to exhibit high catalytic activity in one-pot, three-component reaction of isatins, malononitrile and anilinolactones using choline chloride (ChCl)/urea as a green solvent under microwave irradiation. It provided an efficient method for the synthesis of spirooxindole dihydropyridines in high to excellent yields. The catalytic system can be successfully reused eight times with a small decrease of its catalytic performance. (C) 2016 Elsevier B.V. All rights reserved.