• 文献标题:   Unravelling the growth mechanism of (3,1) graphene nanoribbons on a Cu(111) surface
  • 文献类型:   Article
  • 作  者:   GEAGEA E, JEANNOUTOT J, MORGENTHALER L, LAMARE S, ROCHEFORT A, PALMINO F, CHERIOUX F
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1039/d1cc01173a EA MAY 2021
  • 出版年:   2021

▎ 摘  要

The growth of graphene nanoribbons has been widely investigated on metal surfaces in an ultrahigh vacuum. Here, we re-investigate the growth of graphene nanoribbons obtained by thermal annealing of 9,9 '-bianthryl derivatives on a Cu(111) surface by using scanning tunnelling microscopy. On the basis of our results, we propose to complete the reaction mechanism commonly accepted in the literature by adding an intramolecular hydrogen atom transfer from the 2,2 '-positions to the 10,10 '-positions as a key-step in the formation of (3,1)-graphene nanoribbons on a Cu(111) surface.