• 文献标题:   Graphene oxide templated nitrogen-doped carbon nanosheets with superior rate capability for sodium ion batteries
  • 文献类型:   Article
  • 作  者:   LUO ZG, ZHOU J, CAO XX, LIU SN, CAI YS, WANG LR, PAN AQ, LIANG SQ
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   19
  • DOI:   10.1016/j.carbon.2017.06.038
  • 出版年:   2017

▎ 摘  要

Doping of N atoms into the carbonacous materials can generate extrinsic defects and more active sites, improve electrode wettability and also broaden the interlayer distance of carbon, hence promote Na storage capacity and high rate capability. Herein, we report the nitrogen-doped carbon nanosheets materials (PPyCs) obtained from pyrolysis of Polypyrrole coated graphene oxides. The pyrolysis temperature plays an important role on the electrochemical performance of PPyCs. With thermal treatment at 400, 600 and 800 degrees C, PPyCs have different content of N doping, and the doped N shows different existential forms. The PPyCs thermal treated at 600 degrees C (PPyC-600) exhibit a reversible capacity of 388.8 mA h g(-1) at a current density of 100 mA g(-1), and even at a high current density of 10 A g(-1), high capacity of 198.6 mA h g(-1) is maintained after 10,000 cycles, demonstrating outstanding cyclic stability, and high-rate capability. Furthermore, the assembled NVP/PPyC-600 full-cell demonstrates a high capacity of 122.2 mA h g(-1) at a current density of 100 mA g(-1) after 100 cycles, indicating the practical application of PPyCs nanosheets anode in sodium ion batteries. (C) 2017 Elsevier Ltd. All rights reserved.