• 文献标题:   Rational in-situ construction of three-dimensional reduced graphene oxide supported Li2S/C composite as enhanced cathode for rechargeable lithium-sulfur batteries
  • 文献类型:   Article
  • 作  者:   WANG DH, XIA XH, XIE D, NIU XQ, GE X, GU CD, WANG XL, TU JP
  • 作者关键词:   lithium sulfide, reduced graphene oxide, carbon matrix, lithiumsulfur battery
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   39
  • DOI:   10.1016/j.jpowsour.2015.09.002
  • 出版年:   2015

▎ 摘  要

The construction of advanced cathode materials is indispensable and vital for developing high-performance lithium-sulfur batteries. Herein, we develop a facile in-situ route to synthesize three-dimensional reduced graphene oxide supported Li2S/carbon composite (3D-rGO-Li2S/C). The Li2S/C nanoparticles are intimately anchored on the surface of 3D-rGO forming an integrated 3D porous composite. Due to the improved conductivity and reduced polysulftde dissolution, the 3D-rGO-Li2S/C cathode exhibits enhanced electrochemical performances with a high initial capacity of 819 mAh g(-1) at 0.1C, as well as good cycling stability with a capacity retention of 415 mAh g(-1) after 100 cycles at 1C. The integrated 3D conductive network is responsible for the enhancement of the electrochemical properties by providing fast ion/electron transfer and high mechanical stability. (C) 2015 Elsevier B.V. All rights reserved.