• 文献标题:   Critical investigation of up-conversion and dual emission from nitrogen functionalized graphene quantum dots
  • 文献类型:   Article
  • 作  者:   SIDDIQUE A, MUKHUTI K, CHOUDHURY S, PRAMANICK AK, HOSSAIN SM, RAY M
  • 作者关键词:   graphene quantum dot, photoluminescence, upconversion, dualband emission, measurement artefact
  • 出版物名称:   JOURNAL OF LUMINESCENCE
  • ISSN:   0022-2313 EI 1872-7883
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jlumin.2022.118763 EA FEB 2022
  • 出版年:   2022

▎ 摘  要

Up-conversion photoluminescence (UCPL) and dual-band photoluminescence (DBPL) are two widely-reported, exotic properties of graphene quantum dots (GQDs). However, both these phenomena can be associated with measurement artefacts. In case of excitation with monochromatic radiation derived from a white light source, the second order of the excitation or the emission signal can cause misleading impressions of UCPL and DBPL. Laser excitations can also generate spurious UCPL and/or DBPL signals due to leaking radiations. Using a spatially separated femtosecond pulsed laser, we find that in nitrogen-functionalized GQDs there is no evidence for DBPL although a real UCPL is hidden behind spurious signals.