• 文献标题:   Studies on Conducting Polypyrrole/Graphene Oxide Composites as Supercapacitor Electrode
  • 文献类型:   Article
  • 作  者:   KONWER S, BORUAH R, DOLUI SK
  • 作者关键词:   polypyrrole, graphene oxide, electrical conductivity, capacitance, supercapacitor
  • 出版物名称:   JOURNAL OF ELECTRONIC MATERIALS
  • ISSN:   0361-5235 EI 1543-186X
  • 通讯作者地址:   Tezpur Univ
  • 被引频次:   97
  • DOI:   10.1007/s11664-011-1749-z
  • 出版年:   2011

▎ 摘  要

An electrode material based on polypyrrole (PPy) doped with graphene oxide (GO) sheets was synthesized via in situ polymerization of pyrrole in the presence of GO in various proportions (5% and 10%). The synthesized samples were characterized by Fourier-transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-vis) absorption spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), x-ray diffraction (XRD) analysis, and electrical conductivity measurements. FTIR spectroscopy and XRD revealed the interaction between GO and PPy. The direct-current (DC) electrical conductivity (75.8 S/cm) of the prepared composites was dramatically enhanced compared with pure PPy (1.18 S/cm). High specific capacitance of PPy/GO composite of 421.4 F/g was obtained in the potential range from 0 V to 0.50 V at 2 mA compared with 237.2 F/g for pure PPy by galvanostatic charge-discharge analysis. Incorporation of GO into the PPy matrix has a pronounced effect on the electrical conductivity and electrochemical capacitance performance of PPy/GO nanocomposites.