• 文献标题:   A review on recent advancements on removal of harmful metal/metal ions using graphene oxide: Experimental and theoretical approaches
  • 文献类型:   Review
  • 作  者:   DESHWAL N, SINGH MB, BAHADUR I, KAUSHIK N, KAUSHIK NK, SINGH P, KUMARI K
  • 作者关键词:   graphene oxide, heavy metal, metal ion, remediation, computational calculation
  • 出版物名称:   SCIENCE OF THE TOTAL ENVIRONMENT
  • ISSN:   0048-9697 EI 1879-1026
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.scitotenv.2022.159672 EA NOV 2022
  • 出版年:   2023

▎ 摘  要

Graphene oxide is a two-dimensional carbon nanomaterial and has gained huge popularity over the last decade. Because, the graphene oxide can be dispersed in water easily and it is one of the most researched two-dimensional ma-terials in the current time. The extraordinary properties shown by graphene oxide (GO) are due to its unique chemical structure; includes various hydrophilic functional groups containing oxygen such as carboxyl, hydroxyl, carbonyl and tiny sp2 carbon domains surrounded by sp3 domains. These groups are very peculiar for various applications as they allow covalent functionalisation with a plethora of compounds. Large surface area, intrinsic fluorescence, excellent surface functionality, amphiphilicity, improved conductivity, high adsorption capacity and superior biocompatibility are some of the chemical properties have drawn research from various fields. Graphene oxide has various interactions such as coordination, chelation, hydrogen bonding, electrostatic interaction, hydrophobic effects, pi-pi interaction, acid base interaction etc., with various metal ions. This review is focused on the removal of metals and metal ions due to their interactions mentioned above. Further, potential of composites of graphene oxide in the removal of metal and metal ions is also discussed. Further, the current challenges in this field at industrial-scale are also discussed.