• 文献标题:   Diffusion-induced stresses in graphene-based composite bilayer electrode of lithium-ion battery
  • 文献类型:   Article
  • 作  者:   LIU DY, CHEN WQ, SHEN XD
  • 作者关键词:   diffusioninduced stresse, graphenebased composite electrode, graphene platelet, stoney formula
  • 出版物名称:   COMPOSITE STRUCTURES
  • ISSN:   0263-8223 EI 1879-1085
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   7
  • DOI:   10.1016/j.compstruct.2017.01.011
  • 出版年:   2017

▎ 摘  要

The diffusion-induced stresses in a bilayer electrode composed of a current collector and a composite active plate of lithium-ion battery are evaluated analytically. The active plate of the bilayer electrode is reinforced by graphene platelets (GPLs), with the corresponding material properties predicted by the combination of the well-established Halpin-Tsai model and the rule of mixture. The diffusion-induced stresses and curvature of the bilayer electrode under either galvanostatic or potentiostatic charging operation are derived. In addition, modified Stoney formulas for the bilayer electrode are developed for the two charging operations. A parametric study is conducted through numerical examples, with a particular focus on the reinforcing effect of GPLs on the stresses and deformation in the bilayer electrode. The size effects of GPLs, including width, length and thickness, on the stresses and deformation are also discussed. (C) 2017 Elsevier Ltd. All rights reserved.