• 文献标题:   Graphene oxide/copper terephthalate composite as a sensing platform for nitrite quantification and its application to environmental samples
  • 文献类型:   Article
  • 作  者:   SUMA BP, PANDURANGAPPA M
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Bangalore Univ
  • 被引频次:   4
  • DOI:   10.1007/s10008-019-04454-8
  • 出版年:   2020

▎ 摘  要

A robust electrochemical sensing platform based on graphene oxide-copper terephthalate (GO/Cu-tpa) composite has been fabricated. The prepared composite was characterized through FTIR, XRD, SEM, and EDS techniques. The electrochemical characterization of the composite was studied after immobilizing the composite material as a thin film on the glassy carbon electrode through voltammetry techniques. The fabricated electrode exhibited an excellent electrocatalytic activity in the oxidation of nitrite. The sensor showed a linear response in the concentration range 5 - 625 mu M with a detection limit of 0.3 mu M and sensitivity of 0.86 +/- 0.06 mu A mu M-1 cm(-2). The electrochemical sensor was validated by measuring the trace level nitrite from water samples, and the results are in good agreement with the standard protocol. Schematic representation of GO/Cu-terepthalate composite preparation and fabrication of nitrite sensor