▎ 摘　　要

Manganese oxide/reduced graphene oxide (MnO2/rGO) hybrid with layered MnO2 nanosheets grow on rGO surfaces have been prepared for microwave absorbing. The hybrid exhibits significantly enhanced microwave absorption properties compared with rGO and MnO2. A maximum reflection loss value can reach -26.7dB at 11.04GHz with the matching thickness of 2.6mm, and the effective absorption bandwidths exceeding -10dB and -20dB are 3.6GHz and 1.06GHz, respectively. The enhancement in microwave absorption efficiency of MnO2/rGO hybrid is arose from the synergistic effects between lamellar MnO2 and rGO in its unique three-dimensional (3D) architecture, which leads to strong conduction loss and multiple reflections, and further in favour of appropriate impedance matching ratio and good attenuation ability. These fundamental understandings on the property-structure relationship of as-synthesized MnO2/rGO hybrid will prove an efficient approach to the designing and construction of MnO2-based 3D nanostructures for advanced electromagnetic wave absorbing applications.