• 文献标题:   TiO2 nanotubes wrapped with reduced graphene oxide as a high-performance anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHENG P, LIU T, SU Y, ZHANG LF, GUO SW
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Shaanxi Univ Sci Technol
  • 被引频次:   26
  • DOI:   10.1038/srep36580
  • 出版年:   2016

▎ 摘  要

Through electrostatic interaction and high-temperature reduction methods, rGO was closely coated onto the surface of TiO2 nanotubes. Even at a high temperature of 700 degrees C, the nanotube morphology of TiO2 (anatase) was preserved because of the assistance of rGO, which provides a framework that prevents the tubes from breaking into particles and undergoing a phase transformation. The rGO/TiO2 nanotubes deliver a high capacity (263 mAh g(-1) at the end of 100 cycles at 0.1 A g(-1)), excellent rate performance (151 mAh g(-1) at 2A g(-1) and 102 mAh g(-1) at 5 A g(-1)), and good cycle stability (206 mAh g(-1) after 500 cycles at 0.5A g(-1)). These characteristics arise from the GO/TiO2 nanotubes' advanced structure. First, the closely coated rGO and Ti3+ in the tubes give rise to a high electro-conductivity of the nanotubes. Additionally, the Li (vertical bar) ions can rapidly transfer into the electrode via the nanotubes' empty inner diameter and short tube wall.