• 文献标题:   Study on the acid-base surface property of the magnetite graphene oxide and its usage for the removal of radiostrontium from aqueous solution
  • 文献类型:   Article
  • 作  者:   CHEN H, LI JX, ZHANG SW, REN XM, SUN YB, WEN T, WANG XK
  • 作者关键词:   magnetite graphene oxide, sr ii, acidbase titration, surface complexation, adsorption
  • 出版物名称:   RADIOCHIMICA ACTA
  • ISSN:   0033-8230
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   21
  • DOI:   10.1524/ract.2013.2099
  • 出版年:   2013

▎ 摘  要

Acid-base titrations of magnetite/graphene oxide (M/GO) and Sr(II) adsorption onto M/GO were operated to investigate surface properties of M/GO and surface complexation bonding interactions between Sr(II) and M/GO. Experimental results showed that Sr(II) adsorption onto M/GO was facilitated by a high pH value and a low ionic strength. Modeling results exhaustively explained the changes of adsorption morphological at different pH and ionic strengths. Thermodynamic parameters (Delta H degrees, Delta S degrees, and Delta G degrees) calculated from the adsorption isotherms showed the adsorption of Sr(II) onto M/GO composite was an endothermic and spontaneous process. M/GO could be separated by magnetic separation from aqueous solution in large scale. The adsorption performance suggests M/GO could be a promising adsorbent material for the preconcentration and separation of radiostrontium from aqueous solution in radionuclide pollution cleanup.