• 文献标题:   Facile fabrication of thermally reduced graphene oxide-platinum nanohybrids and their application in catalytic reduction and dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   KHOA NT, THUAN VD, KIM SW, PARK S, TAM VT, CHOI WM, CHO S, KIM EJ, HAHN SH
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   5
  • DOI:   10.1039/c5ra21896a
  • 出版年:   2016

▎ 摘  要

We report the fast synthesis of thermally reduced graphene oxide : platinum (TRGO : Pt) nanohybrids by simply spraying a GO:Pt4+ solution on a hot plate. X-ray photoelectron spectroscopy and atomic force microscopy analyses are performed to investigate the thermal reduction of GO:Pt4+ and the morphologies of the TRGO : Pt hybrid monolayer, respectively. The catalytic performance of TRGO : Pt is evaluated for the reduction of o-nitroaniline. A significant increase in the reaction rate constant for TRGO : Pt compared with pure Pt is due to facilitated electron transfer at the TRGO : Pt interface and enhanced catalytic active sites. Effective electron transfer from TRGO to Pt and significantly increased catalytic active sites in hybrids suggest that TRGO : Pt is a highly potential counter electrode material in dye-sensitized solar cells (DSSCs). The hybrid provides numerous electrons to I-/I3(-) electrolyte to reduce the recombination at the interface. As a result, the performance of DSSCs with the TRGO : Pt hybrid electrode is significantly increased by 34% in comparison with a pure Pt electrode.