• 文献标题:   Surfactant-Free, Stable Noble Metal-Graphene Nanocomposite as High Performance Electrocatalyst
  • 文献类型:   Article
  • 作  者:   MONDAL A, JANA NR
  • 作者关键词:   graphene, nanoparticle, nanocomposite, catalyst, fuel cell
  • 出版物名称:   ACS CATALYSIS
  • ISSN:   2155-5435
  • 通讯作者地址:   Indian Assoc Cultivat Sci
  • 被引频次:   55
  • DOI:   10.1021/cs401032p
  • 出版年:   2014

▎ 摘  要

Preparation of a noble metal-graphene nanocomposite (MGN)-based clean and stable catalyst with uniform distribution of ultrafine nanoparticles can greatly improve the performance of fuel cells. Here, we show that surfactant-free MGNs for different noble metals can be prepared for high-performance fuel cell catalysis by the reaction of respective ultrasmall colloidal metal oxide/hydroxides with partially reduced colloidal graphene oxide. The resultant MGN is composed of highly dispersed M-M+n based nanoparticles of ultrasmall size and produces a strong and stable catalytic current for ethanol and formic acid oxidation.