• 文献标题:   Edge Oxidation Effect of Chemical-Vapor-Deposition-Grown Graphene Nanoconstriction
  • 文献类型:   Article
  • 作  者:   IQBAL MW, IQBAL MZ, JIN X, HWANG C, EOM J
  • 作者关键词:   graphene, edge oxidation, nanoconstriction, doping, raman spectroscopy, transport
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Sejong Univ
  • 被引频次:   19
  • DOI:   10.1021/am405885c
  • 出版年:   2014

▎ 摘  要

The edge oxidation effects of chemical-vapor-deposition-grown graphene devices with nanoconstrictions of different sizes are presented. The effects of edge oxidation on the doping level of a nanoconstriction graphene device were identified by Raman spectroscopy and using the back-gate-voltage-dependent resistance. Strong p-type doping was observed as the size of nanoconstriction decreased. The Dirac point of the graphene device shifted toward positive voltage, and the positions of the G and 2D peaks in Raman spectroscopy shifted toward a higher wave number, indicating the p-type doping effect of the graphene device, p-type doping was lifted by deep-ultraviolet light illumination under a nitrogen atmosphere at room temperature. p-type doping was restored by deep-ultraviolet light illumination under an oxygen atmosphere at room temperature. Edge oxidation in the narrow structures explains the origin of the p-type doping effect widely observed in graphene nanodevices.