• 文献标题:   Photo-reduction assisted synthesis of MnO2/reduced graphene oxide/P25 for electrochemical detection of hydrogen peroxide
  • 文献类型:   Article
  • 作  者:   CUI SF, LI Y, DENG DM, ZENG LL, YAN XX, QIAN J, LUO LQ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   10
  • DOI:   10.1039/c5ra13275d
  • 出版年:   2016

▎ 摘  要

In this work, we report the synthesis of MnO2/RGO (reduced graphene oxide)/P25 nanocomposites for a non-enzymatic hydrogen peroxide sensor. MnO2/RGO/P25 nanocomposites were synthesized with a photo-reduction approach and characterized by field emission scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and Raman spectroscopy. A non-enzymatic hydrogen peroxide sensor was fabricated by dropping MnO2/RGO/P25 nanocomposites on the surface of a glassy carbon electrode. Electrochemical measurements of the MnO2/RGO/P25 modified electrode were carried out on an electrochemical workstation. The as-prepared sensor exhibited high electrocatalytic activity, selectivity and stability towards the oxidation of H2O2. Under optimum conditions, the calibration curve for H2O2 determination was linear in the range from 1.0 x 10(-6) to 4.0 x 10(-3) M (R-2 = 0.999) with a detection limit of 3 x 10(-7) M (S/N = 3).