▎ 摘 要
In this work, we report the synthesis of MnO2/RGO (reduced graphene oxide)/P25 nanocomposites for a non-enzymatic hydrogen peroxide sensor. MnO2/RGO/P25 nanocomposites were synthesized with a photo-reduction approach and characterized by field emission scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy and Raman spectroscopy. A non-enzymatic hydrogen peroxide sensor was fabricated by dropping MnO2/RGO/P25 nanocomposites on the surface of a glassy carbon electrode. Electrochemical measurements of the MnO2/RGO/P25 modified electrode were carried out on an electrochemical workstation. The as-prepared sensor exhibited high electrocatalytic activity, selectivity and stability towards the oxidation of H2O2. Under optimum conditions, the calibration curve for H2O2 determination was linear in the range from 1.0 x 10(-6) to 4.0 x 10(-3) M (R-2 = 0.999) with a detection limit of 3 x 10(-7) M (S/N = 3).