• 文献标题:   Coherent phonons in carbon nanotubes and graphene
  • 文献类型:   Article
  • 作  者:   KIM JH, NUGRAHA ART, BOOSHEHRI LG, HAROZ EH, SATO K, SANDERS GD, YEE KJ, LIM YS, STANTON CJ, SAITO R, KONO J
  • 作者关键词:   carbon nanotube, graphene, graphene nanoribbon, coherent phonon, ultrafast dynamic
  • 出版物名称:   CHEMICAL PHYSICS
  • ISSN:   0301-0104 EI 1873-4421
  • 通讯作者地址:   Rice Univ
  • 被引频次:   16
  • DOI:   10.1016/j.chemphys.2012.09.017
  • 出版年:   2013

▎ 摘  要

We review recent studies of coherent phonons (CPs) corresponding to the radial breathing mode (RBM) and G-mode in single-wall carbon nanotubes (SWCNTs) and graphene. Because of the bandgap-diameter relationship, RBM-CPs cause bandgap oscillations in SWCNTs, modulating interband transitions at terahertz frequencies. Interband resonances enhance CP signals, allowing for chirality determination. Using pulse shaping, one can selectively excite specific-chirality SWCNTs within an ensemble. G-mode CPs exhibit temperature-dependent dephasing via interaction with RBM phonons. Our microscopic theory derives a driven oscillator equation with a density-dependent driving term, which correctly predicts CP trends within and between (2n + m) families. We also find that the diameter can initially increase or decrease. Finally, we theoretically study the radial breathing like mode in graphene nanoribbons. For excitation near the absorption edge, the driving term is much larger for zigzag nanoribbons. We also explain how the armchair nanoribbon width changes in response to laser excitation. (C) 2012 Elsevier B.V. All rights reserved.