• 文献标题:   Synthesis of graphene quantum dots with temperature-sensitive properties from sea rice for rapid and highly selective detection of 4-nitrophenol
  • 文献类型:   Article
  • 作  者:   LUO K, LUO XY, WU YL, LIANG ZB, KANG XH, WEN YM
  • 作者关键词:   biomas, fluorescence, 4nitrophenol detection, green synthesi, temperaturesensitive, graphene quantum dot
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.diamond.2023.109849 EA MAR 2023
  • 出版年:   2023

▎ 摘  要

The green transformation of biomass materials into carbon nanomaterials with high application value has always been of great interest. In this study, we successfully synthesized temperature-sensitive and narrow-size distribution graphene quantum dots (GQDs) via mild oxidation, which were derived from 250 degrees C carbonized sea rice. This synthetic approach is green, supports large-scale operations, and consumes low amounts of energy. Through the use of TEM, DLS, AFM, XRD, Raman, FTIR, XPS, UV-vis, and PL technologies characterized GQDs. The GQDs exhibited good dispersion, temperature-sensitive properties, light stability, and tunable photoluminescence. The GQDs particle sizes were 1.20 +/- 0.40 nm, and lambda em = 458 nm at 340 nm excitation. Furthermore, we successfully detected trace amounts of 4-nitrophenol (4-NP), which exhibited a significant linear correlation between 0 and 1000 mu M; the detection limit was 0.034 mu M. The GQDs fluorescence probe was selective even with the distractors. Additionally, the quenching between the GDQs and 4-NP was caused by the internal filtering effect. Standard recovery experiments indicated that the recovery rates ranged from 97.6 % to 101.3 % for real water samples. Our research serves as a foundation for the creation of high-performance temperature-sensitive sensor devices for use in biomedical and environmental applications.