• 文献标题:   High-quality graphene synthesis on amorphous SiC through a rapid thermal treatment
  • 文献类型:   Article
  • 作  者:   HAN D, WANG X, ZHAO YB, CHEN Y, TANG MX, ZHAO ZQ
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Peking Univ
  • 被引频次:   3
  • DOI:   10.1016/j.carbon.2017.06.002
  • 出版年:   2017

▎ 摘  要

Synthesizing high-quality graphene by catalytic transformation from amorphous silicon carbide (a-SiC) through a rapid thermal treatment (RTT) method is reported. SiO2/Si substrates are coated by a-SiC films followed by Cu and Ni films deposited sequentially. The samples are then thermally annealed by RTT for the synthesis of high-quality graphene in only 3 min. The synergistic effect of Cu and Ni catalyst is observed. We conjecture that the inserted copper film acts not only as a catalyst or substrate for graphene growth but also as a barrier for carbon diffusion to facilitate the synthesis of monolayer graphene, while the nickel film acts as another catalyst and forms Cu-Ni alloy to lower the catalytic temperature. In this paper, we present a simple and time-saving way in preparation of high-quality graphene and put forward a brief theoretical model for the growth of graphene. (C) 2017 Published by Elsevier Ltd.