• 文献标题:   Evaluation of Exfoliated Graphite to Graphene in Polyamide 66 Using Novel High Shear Elongational Flow
  • 文献类型:   Article
  • 作  者:   HENDRIX JW, SZETO R, NOSKER T, LYNCHBRANZOI J, EMGE TJ
  • 作者关键词:   graphene, graphene polymer matrix composite, polyamide 66, elongational flow, hydrogen bond
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:   Rutgers State Univ
  • 被引频次:   0
  • DOI:   10.3390/polym10121399
  • 出版年:   2018

▎ 摘  要

Graphene has been publicized as the game changing material of this millennium. To this day, scalable production leading to exceptional material properties has been difficult to attain. Most methods require harsh chemicals, which result in destroying the graphene surface. A method was developed, exploiting high speed elongational flow in a novel designed batch mixer; creating a distribution of pristine few to many layer graphene flakes. The method focuses on exfoliating in a molten polyamide 66 (PA66) matrix, creating a graphene reinforced polymer matrix composite (G-PMC). The process revealed that high speed elongational flow was able to create few layer graphene. Graphite exfoliation was found driven in part by diffusion, leading to intercalation of PA66 in graphite. The intercalated structure lead to increases in the hydrogen bonding domain, creating anisotropic crystal domains. The thermal stability of the G-PMC was found to be dependent to the degree of exfoliation, PA66 crystal structure and composite morphology. The aim of this research is to characterize uniquely produced graphene containing polymer matrix composites using a newly created elongational flow field. Using elongational flow, graphite will be directly exfoliated into graphene within a molten polymer.