• 文献标题:   Graphene-based Oxygen Reduction Electrodes for Low Temperature Solid Oxide Fuel Cells
  • 文献类型:   Article
  • 作  者:   JEE Y, KARIMAGHALOO A, MACEDOANDRADE A, MOON H, LI Y, HAN JW, JI S, ISHIHARA H, SU PC, CHA SW, TUNG VC, LEE MH
  • 作者关键词:   alternative electrode material, low temperature solid oxide fuel cell, nitrogendoped graphene, oxygen reduction reaction, solid oxide fuel cell
  • 出版物名称:   FUEL CELLS
  • ISSN:   1615-6846 EI 1615-6854
  • 通讯作者地址:   Univ Calif
  • 被引频次:   4
  • DOI:   10.1002/fuce.201600169
  • 出版年:   2017

▎ 摘  要

In this report, we present a study of using nitrogen-doped graphene as the air electrode of low temperature solid oxide fuel cells (LT-SOFCs) operating at 350 degrees C or lower. Three graphene derivatives were prepared through hydrothermal reactions and their electrochemical performance and material properties were characterized in the temperature range of 225-350 degrees C in atmospheric air. Nitrogen-doped graphene was found to exhibit a decent air electrode performance comparable to a porous Pt electrode aged for 8 h at 350 degrees C, but only for a limited time. After similar to 10 h of operation at 350 degrees C, the electrode performance degraded significantly due to carbon oxidation. However, alternative routes of synthesizing/doping graphene derivatives are expected to improve the viability of using these materials as a practical high temperature air electrode.