• 文献标题:   Fabrication of High-Performance PP/Graphene Nanocomposites via Friedel-Crafts
  • 文献类型:   Article
  • 作  者:   ZHANG HX, YAN X, HAN W, LIU C, CHEN YJ, XIA YY, CAI ZG, YOON KB, YANG JM
  • 作者关键词:   composite material, electrical propertie, nanocomposite
  • 出版物名称:   JOURNAL OF INORGANIC ORGANOMETALLIC POLYMERS MATERIALS
  • ISSN:   1574-1443 EI 1574-1451
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s10904-023-02567-2 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

In the past few years, graphene-based nanocomposites are a hot topic in the fields of materials and chemistry owing to their unique features. We describe a facile melt blending method for preparing polypropylene/graphene nanocomposites in this article. The first stage involved grafting graphene onto chlorinated PP using the Friedel-Crafts reaction. The second stage involved the use of the resulting PP grafted graphene (PPG) as fillers in a melt blend with commercial PP. After being grafted with an organic PP chain, graphene becomes lipophilic; consequently, the PPG can be dispersed well within the PP matrix while retaining excellent interface adhesion. As a result, the thermostability, mechanical performance, and electrical conductivity of PP were significantly improved through the addition of PPG fillers. Additionally, with 10 wt% of PPG fillers (equivalent to 5 wt% graphene sheets), the conductivity approaches 6.8 S m(-1). As a result of this research, a new method for producing high-performance PP has been developed.{GRAPHIS}