• 文献标题:   Comparison of the adsorption of cationic blue onto graphene oxides prepared from natural graphites with different graphitization degrees
  • 文献类型:   Article
  • 作  者:   JIAO X, ZHANG LY, QIU YS, GUAN JF
  • 作者关键词:   natural graphite, graphitization degree, graphene oxide, cationic blue, adsorption
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   8
  • DOI:   10.1016/j.colsurfa.2017.05.094
  • 出版年:   2017

▎ 摘  要

In this study, comparative experiments were conducted on the adsorption of cationic blue onto graphene oxides (GOs) synthesized by graphites with various graphitization degrees. XRD, XPS, FT-IR, Raman, AFM and BET were used to characterize the prepared GOs. The results demonstrated that graphites with lower graphitization degrees were more easily oxidized, and GOs prepared from those graphites had more oxygen-containing groups, higher degrees of defects, thinner layers and higher specific surface areas. The equilibrium data was in better agreement with the Langmuir model than both the Freundlich model and the Temkin model. In addition, the adsorption of cationic blue on the GOs was well-described by the pseudo-second order kinetics model according to the kinetic experiments. Moreover, the thermodynamic parameters demonstrated that the adsorption was both an endothermic and spontaneous process.