▎ 摘　　要

Using a sintering process with Prussian Blue (PB) and 20 wt% glucose at high temperature (950 degrees C for 6 hours in Ar/H-2) with oxidation in the air at room temperature, we synthesized a nano-monocrystalline gamma-phase iron oxide (gamma-Fe2O3) compound coated with carbon comprising a number of graphene layers, which was named as core-shell nano-monocrystalline gamma-Fe2O3@graphene. It can be noted that the formation of nano-monocrystal is different from forming core-shell nano-polycrystalline hollow gamma-Fe2O3@graphene sintered at lower temperature (650 degrees C 6 hours in Ar) via a simple Kirkendall process with oxidation at room temperature as reported in our previous study. We further investigate how nanomonocrystalline gamma-Fe2O3 is formed by controlling the synthesis process and testing with TEM and SEM. We confirmed that the nano-monocrystalline gamma-Fe2O3 is grown from nano-monocrystalline Fe with interface catalysis of O-2 and the related mechanism is discussed through comparing the structures of gamma-Fe2O3 and the Fe crystals. The core-shell nano-monocrystalline gamma-Fe2O3@graphene shows high performance as an anode material in Li-ions batteries (much better than nano-polycrystalline hollow gamma-Fe2O3@graphene reported in previous study). For example, the cycling stability and rate performance are remarkable as an anode material for lithium ion batteries with a high reversible capacity of 848.08 and 782.54 mA h g(-1) at 1C and 5C for 600 cycles, respectively, and a high rate performance (284.42 mA h g(-1) at 20C). Another interesting performance is that during the first 80 cycles, the specific capacity increases, which may result from more interface area being generated by the gamma-Fe2O3 nanomonocrystal crushing with protection of the graphene-shell during the initial charging/discharging cycles. This synthesis method and mechanism can be used as a guide to produce gamma-Fe2O3 as an anode material for lithium ion batteries with high performance on a large scale.