• 文献标题:   Extruded PLA Nanocomposites Modified by Graphene Oxide and Ionic Liquid
  • 文献类型:   Article
  • 作  者:   SANCHEZRODRIGUEZ C, AVILES MD, PAMIES R, CARRIONVILCHES FJ, SANES J, BERMUDEZ MD
  • 作者关键词:   pla nanocomposite, extrusion, dma, raman, ftir, graphene, ionic liquid
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.3390/polym13040655
  • 出版年:   2021

▎ 摘  要

Polylactic acid (PLA)-based nanocomposites were prepared by twin-screw extrusion. Graphene oxide (GO) and an ionic liquid (IL) were used as additives separately and simultaneously. The characterization of the samples was carried out by means of Fourier transform infrared (FT-IR) and Raman spectroscopies, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The viscoelastic behavior was determined using dynamic mechanical analysis (DMA) and rheological measurements. IL acted as internal lubricant increasing the mobility of PLA chains in the solid and rubbery states; however, the effect was less dominant when the composites were melted. When GO and IL were included, the viscosity of the nanocomposites at high temperatures presented a quasi-Newtonian behavior and, therefore, the processability of PLA was highly improved.