• 文献标题:   Efficient solution-processed small-molecule solar cells by insertion of graphene quantum dots
  • 文献类型:   Article
  • 作  者:   WANG DH, KIM JK, KIM SJ, HONG BH, PARK JH
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Chung Ang Univ
  • 被引频次:   16
  • DOI:   10.1039/c4nr04944f
  • 出版年:   2014

▎ 摘  要

In this work, we have demonstrated the results of several positive effects that arise from the addition of graphene quantum dots (GQDs) to solution-processed small molecule bulk-heterojunction (SM-BHJ) solar cells fabricated from a p-DTS(FBTTh2)(2)/[6,6]-phenyl C-71 butyric acid methyl-ester (PC71BM). The device with an optimized ratio of GQDs exhibits increased current density and fill factor owing to 10% improved external quantum efficiency (EQE) and induction of a favorable SM-BHJ morphology. Additionally, the multiple scattering of the GQDs in the SM-BHJ leads to longer optical pathlengths according to the analysis of diffuse reflectance spectra and UV/Vis absorption spectra. The GQD inserted SM-BHJ film at the optimized concentration exhibits decreased charge transport resistance significantly by impedance measurements with effective charge extraction in the device which contributes to 15% enhancement of power conversion efficiency (PCE).