▎ 摘 要
In this work, we have demonstrated the results of several positive effects that arise from the addition of graphene quantum dots (GQDs) to solution-processed small molecule bulk-heterojunction (SM-BHJ) solar cells fabricated from a p-DTS(FBTTh2)(2)/[6,6]-phenyl C-71 butyric acid methyl-ester (PC71BM). The device with an optimized ratio of GQDs exhibits increased current density and fill factor owing to 10% improved external quantum efficiency (EQE) and induction of a favorable SM-BHJ morphology. Additionally, the multiple scattering of the GQDs in the SM-BHJ leads to longer optical pathlengths according to the analysis of diffuse reflectance spectra and UV/Vis absorption spectra. The GQD inserted SM-BHJ film at the optimized concentration exhibits decreased charge transport resistance significantly by impedance measurements with effective charge extraction in the device which contributes to 15% enhancement of power conversion efficiency (PCE).