• 文献标题:   Co-electrodeposition of silane and graphene oxide on copper to enhance the corrosion protection performance
  • 文献类型:   Article
  • 作  者:   DU XQ, LIU YW, CHEN DC, ZHANG Z, CHEN Y
  • 作者关键词:   electrodeposition, graphene oxide, copper, corrosion
  • 出版物名称:   SURFACE COATINGS TECHNOLOGY
  • ISSN:   0257-8972 EI 1879-3347
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1016/j.surfcoat.2022.128279 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

In the present work, silane and graphene oxide (GO) nanocomposite was successfully constructed on copper using a facile co-electrodeposition procedure. Structure and composition characterizations revealed that the added GO nanosheets were partially electro-reduced and covalently bonded with silanol groups to form a more compact and uniform nanocomposite, which contributed to the enhanced chemical and mechanical performance of the electrodeposited silane/GO nanocomposite. Electrochemical tests indicated that the corrosion current density was decreased over two orders of magnitude. The protection efficiency was maintained above 99.8% after immersing in 1 mol/L sodium chloride aqueous solution 120 h. Meanwhile, the contact angle and sliding angle of electrodeposited silane/GO nanocomposite varied slightly after abraded 150 cycles, which presented an excellent mechanical durability. According to the above results, this work supplies a feasible and effective strategy for corrosion protection of conducting materials with long-term protectiveness and mechanical robustness in real-life applications.