▎ 摘　　要

In this study, we report the construction of a novel composite photocatalyst (BiVO4/rGH) composed of quantum dots (QDs) self-decorated BiVO4-nanoparticels (NPs) and reduced graphene hydrogel (rGH). The composite structures were prepared using an in-situ growth method. The BiVO4/rGH composite photocatalysts exhibited excellent photocatalytic efficiency for the degradation of tetracycline hydrochloride (TC center dot HCl). The promoted photocatalytic activity of the BiVO4/rGH is attributed to the synergetic effects of the unique structure involving QDs self-decorated BiVO4 NPs and a 3D network structure of rGH, which resulted in higher number of photogenerated charge carriers, surplus active sites, and enhanced charge separation. In addition, trapping measurements showed that center dot O-2(-) and h(+), as the main active species, play a crucial role in the degradation of TC center dot HCl over the composite photocatalyst. This study facilitates the design and construction of high efficiency hybrid photocatalysts with multifunctional materials for the removal of water pollutants. (C) 2021 Elsevier Ltd. All rights reserved.