• 文献标题:   Sandwich-like graphene-supported mesoporous silica nanosheets as sulfur hosts for highly stable lithium-sulfur batteries
  • 文献类型:   Article
  • 作  者:   ZHANG N, XIA M, GE CC
  • 作者关键词:   lithiumsulfur batterie, shuttle effect, polysulfide, sulfur host, mesoporous nanosheet
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Sci Technol Beijing
  • 被引频次:   3
  • DOI:   10.1016/j.jallcom.2020.154189
  • 出版年:   2020

▎ 摘  要

Herein, the sandwich-like graphene-supported mesoporous silica nanosheets (G-mesosilica nanosheets) have been fabricated as sulfur cathode hosts for Li-S batteries. The obtained G-mesosilica nanosheets possess a mesoporous structure with two sizes (2.8 nm and 14 nm) of mesopores, an uniform thickness of similar to 22 nm and a high specific surface area of 966 m(2) g(-1). As the sulfur hosts, the small mesoporous (2.8 nm) in each G-mesosilica nanosheet can effectively prevent the shuttle effect. As a consequence, the sulfur cathodes with unique G-mesosilica nanosheets as the sulfur hosts (G-mesosilica nanosheets/S cathodes) can significantly improve the long-term cycle performance (81% capacity retention after 500 cycles) of Li-S batteries. (C) 2020 Elsevier B.V. All rights reserved.